Swelling and shrinking processes of sodium polyacrylate-type super-absorbent gel in electrolyte solutions.
نویسندگان
چکیده
منابع مشابه
Osmotic swelling of polyacrylate hydrogels in physiological salt solutions.
The swelling behavior of fully neutralized sodium polyacrylate gels was investigated in aqueous solutions of alkali metal (LiCl, NaCl, KCl, CsCl) and alkaline earth metal salts (CaCl2, SrCl2, BaCl2). The total salt concentration and the ratio of monovalent to divalent cations were varied in the biologically significant range. It is found that the concentrations of both monovalent and divalent c...
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The swelling and shrinking behaviors of a series of poly(N-isopropylacrylamide) (PNIPA) hydrogels are studied in aqueous solutions of sodium dodecylbenzenesulfonate (SDBS). Between 0 and 3 mol % 2-acrylamido-2-methylpropanesulfonic acid sodium salt (AMPS) is used as an ionic comonomer in the hydrogel synthesis. It is shown that the collapsed PNIPA gels in water at 52°C start to swell above a cr...
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We investigated the mechanical, swelling, and structural properties of mechanically tough clay/sodium polyacrylate (PAAS) hydrogels prepared by simple mixing. The gels had large swelling ratios, reflecting the characteristics of the constituent polymer. The swelling ratios initially increased with the increase of the swelling time, and then attained maximum values. Afterwards, they decreased wi...
متن کاملEffect of monovalent-divalent cation exchange on the swelling of polyacrylate hydrogels in physiological salt solutions.
The volume transition induced by monovalent-divalent cation exchange of fully neutralized polyacrylate hydrogels was investigated in aqueous NaCl solutions. The variation of the osmotic swelling pressure, shear modulus, and mixing pressure was measured when Na(+) ions were substituted by divalent or trivalent cations. Alkali metal salts move freely throughout the entirely network, and alkaline ...
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ژورنال
عنوان ژورنال: JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
سال: 1990
ISSN: 0021-9592,1881-1299
DOI: 10.1252/jcej.23.119